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Heme oxygenase and heme degradation

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This discovery led to the proposed “floodgate model” in redox signaling, wherein a burst of H 2 O 2 could generate a Cys-sulfinic acid on PRX in a rapid two-step process, which would transiently inactivate the PRX peroxidase activity and allow H 2 O 2 to accumulate locally and oxidize Cys residues on other proteins as a signaling molecule (140)